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In this work, we synthesized a new two-dimensional Cd(Ⅱ) coordination polymer, [Cd(1,4-NDC)(L)](1), by using mixed 1,4-naphthalenedicarboxylic acid(1,4-H_2NDC) and typical chelating N-donor ligands 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenan