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A new 2-naphthate(NA-)-based coordination complex,[Cu3(μ3-OH)4(NA)2]n(1),was hydrothermally prepared and structurally and magnetically characterized.1 crystallizes in the monoclinic P21/c space group with a = 19.990(7),b = 5.616(2),c = 9.179(3) ?,β = 96.536(6)°,V = 1023.8(7) ?3,Dc = 1.950 g/cm3,Mr = 300.49,Z = 4,F(000) = 602,μ = 3.138 mm-1,the final R = 0.0317 and w R = 0.0818 for 4944 observed reflections with I > 2σ(I).Complex 1 exhibits an extended corner-sharing {Cu3(μ3-OH)}5+ triangle-based layered structure with the NA-ligands located on both sides.The interplay of the typical anti-and ferromagnetic interactions mediated by μ3-OH-and μ-syn,syn-carboxylate heterobridges leads to the overall intralayer ferromagnetic couplings of 1.
A new 2-naphthate (NA -) - based coordination complex, [Cu3 (μ3-OH) 4 (NA) 2] n (1) was wasothermally prepared and structurally and magnetically characterized. Crystallizes in the monoclinic P21 / c space group with a = 19.990 (7), b = 5.616 (2), c = 9.179 (3) ?, β = 96.536 (6) °, V = 1023.8 (7)? 3, Dc = 1.950 g / cm3, Mr = 300.49, Z = 4, F (000) = 602, μ = 3.138 mm-1, the final R = 0.0317 and w R = 0.0818 for 4944 observed reflections with I> 2σ (I) .Complex 1 exhibits an extended corner-sharing {Cu3 (μ3-OH)} 5+ triangle-based layered structure with the NA-ligands located on both sides. The interplay of the typical anti-and ferromagnetic interactions mediated by μ3-OH- and μ-syn, syn- carboxylate heterobridges leads to the overall intralayer ferromagnetic couplings of 1.