【摘 要】
：
The 2D-layer compound ([Na2(C8H12N2O3)4(C2H6SO)4(W6O19)]n 1, Mr = 2133.98) synthesized by the reaction of sodium tungstate and barbitone sodium in the solution
【机 构】
：
State Key Laboratory of Structural Chemistry,Fujian University of Technology,Fujian Normal Universit
论文部分内容阅读
The 2D-layer compound ([Na2(C8H12N2O3)4(C2H6SO)4(W6O19)]n 1, Mr = 2133.98) synthesized by the reaction of sodium tungstate and barbitone sodium in the solution of DMSO and water has been characterized by IR and Raman spectra, elemental analysis and TGA.X-ray diffrac- tion analysis indicates that Compound 1 crystallizes in the monoclinic system, space group C2/c with a = 14.8026(4), b = 17.3012(3), c = 19.6379(5) (A), β = 98.6300o, V = 4972.4(2) (A)3, Z = 4, F(000) = 3928, Dc = 2.851 and μ = 14.101 mm-1.1 has a two-dimensional layer structure with hexapolyoxotungstate building blocks and coordinated sodium chains.
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