An algorithm for direction angle of arrival(DOA) estimation and array calibration of signals from multiple mobile users in the CDMA systems and multi-path environment was presented . The main idea is that the algorithm employs code-matched filter and model of the inter-symbol interference and multiple-access interference exactly. The correlation matrices of the received signals before and after code-matched filtering were employed to eliminate the effect of the additive white Gaussian noise, and a new mathematical problem was created, a new maximum likelihood method based on the strong law of large number was derived for DOA estimation and array calibration.Computer simulation results prove that the algorithm is effective.