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客体分子离开沸石中的孔穴后 ,沸石的孔隙率和基体结构可保持不变。以氢键结合的有机物能否模拟这种结构聚集体 ?Ｍｏｎｔｒｅａｌ大学的Ｊ .Ｄ .Ｗｕｅｓｔ等证明有此可能。虽然氢 Ｃ ＮＮＮ ＮＨ2ＮＨ2 4键比沸石中的键要弱 ,但是采用结晶技术可以形成三维结构。用如右图
After the guest molecules leave the pores in the zeolite, the porosity and the matrix structure of the zeolite can remain unchanged. Hydrogen-bonded organics can mimic this structural aggregate? J.W.Wuest of the University of Montreal et al. Demonstrated this possibility. Although the hydrogen C NNN NH2NH2 4 bond is weaker than the bond in the zeolite, a three-dimensional structure can be formed by the crystallization technique. Use as the right figure