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合成了新的锰配合物[Mn(H2O)6](bctrz)2(1),并测定了其晶体结构(bctrz=(4-苯甲酸)三氮唑).晶体属于三斜晶系,空间群P,īa=0.694 66(16),b=0.852 87(17),c=1.010 95(19)nm,α=72.556(12),β=90.109(2),γ=84.596(16)o,V=0.553 8(2)nm3,Z=1,Mr=539.37,Dc=1.617 g/cm3,F(000)=279,μ=0.665 mm-1.对于I>2σ(I)的1 923个衍射点的最终R=0.030 6,wR=0.084 1.锰原子与六个水分子的六个氧原子配位,形成了扭曲八面体的配位环境.通过[Mn(H2O)6]2+和bctrz的氢键作用,配合物1形成了三维网格.
A new manganese complex [Mn (H2O) 6] (bctrz) 2 (1) was synthesized and its crystal structure was determined (bctrz = (4-benzoic acid) Group ,a = 0.694 66 (16), b = 0.852 87 (17), c = 1.010 95 (19) nm, α = 72.556 (12), β = 90.109 (2), γ = 84.596 (16) V = 0.553 8 (2) nm3, Z = 1, Mr = 539.37, Dc = 1.617 g / cm3, F (000) = 279 and μ = 0.665 mm- 1. For 1 923 diffraction of I> 2σ (I) The final R = 0.0306, wR = 0.084 1. The manganese atom coordinated with the six oxygen atoms of six water molecules to form a distorted octahedron coordination environment. [Mn (H2O) 6] 2+ and bctrz Hydrogen bonding, complex 1 formed a three-dimensional grid.