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金属卟啉的分子识别研究是当今卟啉仿生化学的重要课题．手性金属卟啉作为光学活性分子的对映选择识别受体和手性核磁共振试剂［１］尤为引人注目．Ｃｒｏｓｓｌｅｙ等［２］报道了以刚性Ｔｒｏｇｅｒｓ碱为间隔基的手性锌双卟啉对组氨酸甲酯和赖氨酸苯酯的立体选择性识...
Metalloporphyrin molecule recognition research is an important topic of today’s porphyrin biochemistry. Chiral metalloporphyrins as optically active molecules enantioselective recognition receptors and chiral NMR reagents [1] is particularly noticeable. Crossley et al [2] reported the stereoselective recognition of histidine methyl ester and lysine phenyl ester with chiral zinc bis-porphyrin with rigid Trogers base as spacer.