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本文研究了伯胺N_(1923)萃取AgNO_3的性能及不同因素对其分配比的影响,通过多种方法确定其萃合物的组成为[Ag(RNH_2)_2]NO_3;测定并计算出该反应的表观平衡常数及热力学函数,同时分析了萃合物的红外及核磁共振谱。
In this paper, the effect of AgNO 3 extracted by primary amines N_ (1923) and the influence of different factors on the distribution ratio of AgNO_3 were studied. The composition of the extract was determined to be [Ag (RNH_2) _2] NO_3 by various methods. The apparent equilibrium constants and thermodynamic functions of the extracted compounds were also analyzed. The infrared and nuclear magnetic resonance spectra of the extracted compounds were also analyzed.