Synthesis of ZnO nanorods and their optical absorption in visible-light region

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Single crystalline ZnO nanorods were prepared by the hydrothermal method with synthesized ZnCl2·4Zn(OH)2 as the precursor. Morphologies of the nanorods were controlled by various reaction conditions with cetyltrimethylammo-nium bromide (CTAB) as the modifying agent. The nanorods were characterized by XRD, TEM, UV-Vis spectra, and IR spectra. The microstructure of holes in nanosize was observed on the surface of the nanorods. The UV-Vis spectra indicate that the as-prepared ZnO nanorods have absorption of visible-light as well as ultraviolet-light. Therefore, these nanorods may be good candidates for visible-light photocatalysis materials from the viewpoint of practical applications. The reason for visible-light absorption was discussed in this article. Single crystalline ZnO nanorods were prepared by the hydrothermal method with the synthetic ZnCl2 · 4Zn (OH) 2 as the precursor. Morphologies of the nanorods were controlled by various reaction conditions with cetyltrimethylammo-nium bromide (CTAB) as the modifying agent. The nanorods were characterized by XRD, TEM, UV-Vis spectra, and IR spectra. The microstructure of holes in nanosize was observed on the surface of the nanorods. The UV-Vis spectra indicate that the as-prepared ZnO nanorods have absorption of visible-light as well As the ultraviolet-light. Thus, these nanorods may be good candidates for visible-light photocatalysis materials from the viewpoint of practical applications. The reason for visible-light absorption was discussed in this article.
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