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本文用AM1方法研究了酰氧基甲酸酯热分解反应的机理,结果表明这类化合物可消除二氧化碳得到酯;也可消除烯酮得到烷氧基甲酸,后者比前者易于进行.
In this paper, AM1 method was used to study the mechanism of the thermal decomposition reaction of acyloxyformates. The results show that these compounds can eliminate carbon dioxide to get ester, and also eliminate ketene to obtain alkoxy carboxylic acid, the latter is easier than the former.