Efficient degradation of chlorobenzene in a non-thermal plasma catalytic reactor supported on CeO2/H

来源 :环境科学学报(英文版) | 被引量 : 0次 | 上传用户:afdwer213
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Chlorobenzene removal was investigated in a non-thermal plasma reactor using CeO2/HZSM-5 catalysts.The performance of catalysts was evaluated in terms of removal and energy efficiency.The decomposition products of chlorobenzene were analyzed.The results show that CeO2/HZSM-5 exhibited a good catalytic activity,which resulted in enhancements of chlorobenzene removal,energy efficiency,and the formation of lower amounts of by-products.With regards to CO2 selectivity,the presence of catalysts favors the oxidation of by-products,leading to a higher CO2 selectivity.With respect to ozone,which is considered as an unavoidable by-product in air plasma reactors,a noticeable decrease in its concentration was observed in the presence of catalysts.Furthermore,the stability of the catalyst was investigated by analyzing the evolution of conversion in time.The experiment results indicated that CeO2/HZSM-5 catalysts have excellent stability:chlorobenzene conversion only decreased from 78% to 60% after 75 hr,which means that the CeO2/HZSM-5 suffered a slight deactivation.Some organic compounds and chlorinated intermediates were adsorbed or deposited on the catalysts surface as shown by the results of Fourier Transform Infrared (FT-IR) spectroscopy,scanning electron microscope (SEM) and energy dispersive X-ray spectroscopy (EDS) analyses of the catalyst before and after the reaction,revealing the cause of catalyst deactivation.
其他文献
高支模施工技术具有承载力强,施工稳定性好等特点,因此在土建工程施工中广泛应用,高支模施工技术的应用不仅能够提升建筑工程施工质量,同时也能够促进建筑行业的发展.本文从
A highly active visible light-induced BiVO_4 photocatalyst was prepared by a simple co-precipitation method using ammonia solution as a pH adjustor and Triton X
2014年7月8日,国务院批复同意《珠江-西江经济带发展规划》(国函〔2014〕87号),珠江-西江经济带由此正式成为国家战略。交通运输部(以下简称“部”)珠江航务管理局(以下简称
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥
期刊
对激光垂准仪竖轴与激光光轴同轴度的测量方法进行探讨,针对性地提出一个室内测量方案,该方案的可行性分析结果表明其完全能满足普通型激光垂准仪的校准要求.
伴随着我国的经济发展,人民对生活环境的要求也越来越高.建筑的给排水工程建设是关系人民日常生活的重要工程,是建筑工程建设的基础,也是一个施工单位形象与实力的象征.在建
针对红外热像仪系统的通讯数据处理模块,详细描述了一种基于 NIOS II 软核处理器的红外热像仪系统通讯数据处理设计方案,该方案运用 SOPC 进行硬件设计并通过标准 C 语言实现通
曼地亚红豆杉 1年生粗壮枝条顶梢扦插成活率高于基部穗条扦插 ,裸床面扦插成活率高于地膜覆盖扦插。水分和光照是影响扦插成活率的重要因素 The survival rate of 1-year-ol
从精确化管理这一思想出发,在构建工程机械装备技术状况综合评价指标体系的基础上,由专家给出相应指标所对应的权重,运用特征矢量法与模糊综合评价的理论与方法对工程机械装
The swine effluent studied was collected from scale pig farms,located in Yujiang County of Jiangxi Province,China,and duckweed (Spriodela polyrrhiza) was select