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具有特殊键型和催化活性的环戊二烯与过渡金属络合物引起了人们的极大兴趣,并对其光解及电解性质都给予了关注。ElMurr等考察了Cp_2TiCl_2的电解过程,认为通过单电子还原可生成负离子自由基[Cp_2TiCl_2]~-。Losada对Cp_2Ti(NSC)_2的电解还原研究亦得到了类似的结论。为进一步探讨配位基对其电化学性质的影响,本文用电化学和ESR相结
With its special bond and catalytic activity, cyclopentadiene and transition metal complexes have aroused great interest and attention has been given to their photolysis and electrolysis properties. ElMurr et al investigated the electrolysis process of Cp_2TiCl_2 and found that the anion of [Cp_2TiCl_2] ~ can be generated by single electron reduction. Losada on Cp_2Ti (NSC) _2 electrolytic reduction study also got a similar conclusion. In order to further explore the ligand on its electrochemical properties, electrochemical and ESR phase in this paper