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研究了十二烷基硫酸钠(SDS)表而活性剂胶束和预胶束对孔雀绿褪色可逆反应的影响,建立了1-1型可逆反应的胶束催化模型和预胶束催化模型,获得了胶束相中正逆反应的速率常数和预胶束的平均聚集数.结果表明,SDS胶束和预胶束对正反应有禁阻作用,而对逆反应有催化作用.
The effects of SDS and surfactant micelles and premicellar micelles on the reversible reaction of malachite green fading were studied. A micellar catalysis model 1-1 and a premicellar catalysis model of reversible reaction 1-1, The rate constant of micellar phase and the average aggregation number of micellar micelles were obtained. The results showed that the SDS micelles and premicelles had a blocking effect on the positive reaction and a catalytic effect on the reverse reaction.