论文部分内容阅读
研究了马来酸酐与环氧氯丙烷交替共聚,及Fe(acac)3Al(iBu)3α,α’联吡啶络合物(acac= 乙酰丙酮) 催化马来酸酐(MA) 和环氧氯丙烷交替共聚的特征,并用红外光谱,核磁共振谱研究了共聚物的结构。动力学研究表明共聚反应与单体浓度和催化剂浓度均呈一级关系。
The copolymerization of maleic anhydride and epichlorohydrin was studied. The effects of Fe (acac) 3Al (iBu) 3α, α’bipyridyl complex (acac = acetylacetone) on maleic anhydride ) And epichlorohydrin. The structure of the copolymer was studied by IR and NMR. Kinetic studies have shown that the copolymerization reaction with the monomer concentration and catalyst concentration showed a first-class relationship.