在特定的条件下以桂皮醛、二苯基壬四烯酮和氢溴酸为原料合成出了一种环状β-卤代缩醛类化合物—— 2 -( 2 -溴 -2 -苯乙基 ) -1 ,3-二烷 ,在无水碳酸钾的存在下与 5 -对羟基苯基 -1 0 ,1 5 ,2 0 -三苯基卟啉反应合成出了一种新型尾式卟啉—— 5 -{对 -[2 -( 2 -苯乙基 ) -1 ,3-二烷 ]氧基苯基 } -1 0 ,1 5 ,2 0 -三苯基卟啉 ,同时合成了其锌、钌、钯金属配合物 ,并通过电子光谱、元素分析、1 HNMR、IR等光谱手段进行了表征 Under specific conditions, cinnamic aldehyde, diphenyl - nonactenone and hydrobromic acid were used as starting materials to synthesize a cyclic β - haloacetal compound, 2 - (2 - bromo - 2 - phenylethyl Yl) -1,3-dioxane was synthesized by the reaction of 5-p-hydroxyphenyl-150,120-triphenylporphyrin in the presence of anhydrous potassium carbonate Porphyrin-5 - {p- [2 - (2-phenylethyl) -1,3-dioxan] oxyphenyl} -1 0,1 5,2-triphenylporphyrin The complexes of zinc, ruthenium and palladium were synthesized and characterized by means of electron spectroscopy, elemental analysis, 1 H NMR and IR spectroscopy