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The crystal structure and morphology of syndiotactic polystyrene (sPS) melt crystallized in various electrostatic fields have been investigated by using wide angle X ray diffraction (WAXD), differential scanning calorimeter (DSC) and scanning electron microscope (SEM). WAXD and DSC analyses show that sPS is gradually transformed from α phase to β phase with increase of electrostatic intensity. The SEM observations indicate that the morphology of sPS micro crystals is strongly dependent on electrostatic intensity applied to the sample during solidification. The variation of the micro crystals orientation from disordered lamellae to ordered lamellare have been observed with increase of electrostatic intensity.
The crystal structure and morphology of syndiotactic polystyrene (sPS) melt crystallized in various electrostatic fields have been investigated by using wide angle X-ray diffraction (WAXD), differential scanning calorimeter (DSC) and scanning electron microscope that sPS is gradually transformed from α phase to β phase with increase of electrostatic intensity. The SEM of indicate the morphology of sP micro crystals is strongly dependent on electrostatic force applied to the sample during solidification. The variation of the micro crystals orientation from disordered lamellae to ordered lamellare have been observed with increase of electrostatic intensity.