Effect of Sn on the Color and Tarnishing of Cu-Mn-Zn Alloys

来源 :材料科学技术学报(英文版) | 被引量 : 0次 | 上传用户:tiger10208
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The effect of Sn on the color and tishing of Cu-Mn-Zn alloys is investigated quantitatively. Using the CIE LAB color system,color parameters such as L*, a* and b* are selected to describe the surface color of alloys while the color difference (△E*)is used to evaluate the color stability. The results show that with the increase of Sn, the color change of Cu-Mn-Zn alloys is greatly reduced and the corrosion resistance in the synthetic sweat is improved dramatically. However, up to 4.4 wt pct Sn does not change the color of Cu-Mn-Zn alloys much. XPS and AES are employed to analyze the tished surface. It is proved that a Sn enriched film is formed and Sn takes the form of Sn oxide. This thin and protective oxide film can prevent alloy from further tishing.
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