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多酸具有多样的拓扑结构和优异的理化性质,在催化、光电材料和药物等领域显示出广阔的应用前景。多酸-有机聚合物超分子自组装杂化材料不仅有效融合了多酸丰富的功能特性和有机聚合物良好的加工性,而且其有序的自组装结构还赋予材料更多优异的功能调控性。静电复合、氢键作用、共价键连等超分子策略是将多酸引入到聚合物基质中的有效方法。本文总结了多酸-有机聚合物超分子杂化材料近几年的最新研究进展,重点介绍了这类杂化材料的构筑策略、其有序的自组装行为以及超分子功能特性的调控等。
Polyoxometalates have diverse topologies and excellent physicochemical properties, showing promising applications in catalysis, optoelectronic materials and pharmaceuticals. The polyacid-organic polymer supramolecular self-assembled hybrid material not only effectively combines the plentiful acid-rich functional properties and the good processability of the organic polymer, but also the ordered self-assembled structure also confers more excellent functional regulation on the material . Supramolecular strategies such as electrostatic recombination, hydrogen bonding, and covalent bonding are effective methods for introducing polyacids into polymer matrices. This review summarizes the latest research progress of polyacid-organic polymer supramolecular hybrid materials in recent years, and focuses on the construction strategy, the ordered self-assembly behavior and the regulation of supramolecular functional properties.