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本文采用Laplace变换方法对二组分和三组分单分子反应的一级反应动力学中反应机理和速率常数的辩识问题进行了系统地讨论。根据讨论结果,从理论上证明了线性反应动力学系统的反应机理和速率常数一般不具有唯一性。
In this paper, the Laplace transform method is used to systematically discuss the reaction mechanism and the rate constant in the first-order reaction kinetics of two-component and three-component single-molecule reactions. According to the results of the discussion, it is theoretically proved that the reaction mechanism and the rate constant of the linear reaction kinetics system are generally not unique.