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采用准经典轨线方法研究了三个不同碰撞能下,反应C(~3P)+NO(X~2Ⅱ)→CN(X~2∑~+)+O(~3P)在Nyman等拟合的两个势能面(~2A″和~2A′)上反应物与产物之间的矢量相关.结果表明在两个势能面上产物的转动角动量矢量不仅取向,而且沿着y轴垂直于散射平面定向,产物的角动量定向依赖于碰撞能和势能面.同时,计算的四个重整化极化依赖微分截面显示产物在三个散射角被强烈极化,这与在两个势能面上的三个过渡态有关.
The quasiclassical trajectory method was used to study the effects of three different collision energies on the Nystag fitting of the reaction C (~ 3P) + NO (X ~ 2Ⅱ) → CN (X ~ 2Σ ~ +) + O The vector correlation between reactants and products on the two potential energy surfaces (~ 2A "and ~ 2A ’) shows that the momentum vector of the rotation angle of the product on both potential surfaces is not only oriented but also perpendicular to the scattering plane Orientation, the angular momentum of the product depends on the collision energy and the potential energy surface.At the same time, the calculated four renormalization polarizations rely on differential cross-section display products are strongly polarized at three scattering angles, which is in the two potential surfaces Three transitional states.