【摘 要】
:
The crosslinked chitosan was grafted by 4-formal benzo-15-crown-5 to obtaine crosslinked chitosan with 4-formal benzo-15-crown-5(CCTS-N=CH-B-15-C-5). Then it wa
【机 构】
:
College of Resource and Environmental Science,College of Chemical Engineering
【出 处】
:
武汉理工大学学报(材料科学版)(英文版)
论文部分内容阅读
The crosslinked chitosan was grafted by 4-formal benzo-15-crown-5 to obtaine crosslinked chitosan with 4-formal benzo-15-crown-5(CCTS-N=CH-B-15-C-5). Then it was loaded with palldium chloride to gain the heterogeneous catalyst, which was easily isolated from the reaction system. The influences of the Pd content of the catalyst, solvent, and temperature on asymmetric hydrogenation of α-phenylethanone have been studied. The catalyst has been found to catalyze the hydrogenation of α-phenylethanone into the chiral alcohol,α-phenyl ethanol under the mild condition. The optical yield of (R)-l-phenylethanol could be obtained as 97.1% under the following conditions: temperature, 30 ℃; solvent, ethanol; Pd content, 1.43 mmol/g; substrate concentration, 0.02 g/mL due to the cooperative effect of crown ether and chitosan polymer. The stability of this catalyst was also studied at the same time. This chiral natural crosslinked chitosan-palladium complex catalyst could be reused without appreciable change in optical catalytic activity, which will be useful for designing crosslinked-chitosan-based adsorption for metal ions for asymmetric hydrogenation.
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