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水溶液中稀土离子不容易与水溶性卟啉如了TPPS_4形成络合物,一般要在非水介质中先行合成。本文在丙酮介质中(含0.1mol/LTEAP)有H_2TPP存在下加入Eu(ClO_4)_3,立即
Rare earth ions in aqueous solution is not easy to form complexes with water-soluble porphyrin TPPS_4, generally in non-aqueous medium first synthesis. In this paper, Eu (ClO_4) _3 was added in the presence of H 2 TPP in acetone medium (containing 0.1 mol / LTEAP)