【摘 要】
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A shape-memory double network hydrogel consists of two polymer networks:a chemically crosslinked primary network that is responsible for the permanent shape and a physically crosslinked secondary network that is used to fix the temporary shapes.The format
【机 构】
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George W Woodruff School of Mechanical Engineering,Georgia Institute of Technology,Atlanta,GA 30332,
论文部分内容阅读
A shape-memory double network hydrogel consists of two polymer networks:a chemically crosslinked primary network that is responsible for the permanent shape and a physically crosslinked secondary network that is used to fix the temporary shapes.The formation/melting transition of the secondary network serves as an effective mechanism for the double network hydrogel\'s shape-memory effect.When the crosslinks in the secondary network are dissociated by applying an external stimulus,only the primary network is left to support the load.When the secondary network is re-formed by removing the stimulus,both the primary and secondary networks support the load.In the past,models have been developed for the constitutive behaviors of double network hydrogels,but the model of shape-memory double network hydrogels is still lack-ing.This work aims to build a constitutive model for the polyacrylamide-gelatin double network shape-memory hydrogel developed in our previous work.The model is first calibrated by experimental data of the double network shape-memory hydrogel under uniaxial loading and then employed to predict the shape-fixing performance of the hydrogel.The model is also implemented into a three-dimension finite element code and utilized to simulate the shape-memory behavior of the double network hydrogel with inhomogeneous deformations related to applications.
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