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对酯交换法生产碳酸二甲酯反应中的催化剂的研究结果进行综述,从环状碳酸酯的结构特性、催化剂的活性中心和酯交换机理等方面对催化剂的问题进行评述,解析了国内外相关的研究成果及他们的可利用性,提出用于提高生产效率和减低生产成本的技术改革建议。
This review summarizes the results of the studies on the catalysts for the production of dimethyl carbonate by transesterification and reviews the catalyst problems from the aspects of the structural characteristics of the cyclic carbonate, the active site of the catalyst and the transesterification mechanism, and analyzes the correlation between the catalysts at home and abroad Research results and their availability, propose technical reform proposals to increase production efficiency and reduce production costs.