光学活性的膦配体在过渡金属催化的不对称合成中起着非常重要的作用 .到目前为止 ,已相继出现 2 0 0 0多个新手性膦配体 .经多年的大量研究积累 ,以 BINAP为代表的几个手性膦配体已用于生产有用的光学活性物质 ,工业上应用的成功极大地推动了手性膦化学的基础研究 .目前 ,对新 Optically active phosphine ligands play a very important role in the transition metal-catalyzed asymmetric synthesis. So far, more than 200 novel phosphine ligands have emerged. After years of extensive research, BINAP Several of the chiral phosphine ligands represented have been used to produce useful optically active substances and the success of industrial applications has greatly contributed to the basic research of chiral phosphine chemistry.At present,