论文部分内容阅读
利用电化学石英晶体微天平（EQCM）手段，结合循环伏安法．计时电流法对六氰亚铁铜（CuHCF)膜修饰电极及其在不同水溶液中的离子交换机制进行了研究。结果表明；通过循环伏安法，在Pt电极上可以牢固地形成CuHCF膜．在氧化还原过程中，不仅是阳离子，阴离子也参与了在CuHCF膜中的传输。
Using electrochemical quartz crystal microbalance (EQCM) means, combined with cyclic voltammetry. Chronoamperometry was used to study the mechanism of CuHCF modified electrode and its ion exchange mechanism in different aqueous solutions. The results show that the CuHCF film can be firmly formed on the Pt electrode by cyclic voltammetry. During the redox process, not only the cation but also the anions are involved in the transport in the CuHCF film.