A Convenient and Practical Prepapation of Acetylphenyl Boronic Acids

来源 :高等学校化学研究(英文版) | 被引量 : 0次 | 上传用户:duanh
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A practical and scalable synthesis route of acetylphenylboronic acids is described. Bromoacetophenones(compounds 3a, 3b) were ketalized with ethylene glycol and triethyl orthoformate to give bromo ketals(compounds 4a-4c) in 60-80% yields. Compounds 4a-4b were treated with a Grignard reagent and then exchanged with borate to give p- and m-acetylphenyl boronic acids(compounds 5a and 5b) in 80% and 56% yields, respectively. The o-form(compound 5c) was obtained in 61% yield via the BuLi method.
其他文献
A series of UV-curable liquid crystalline diacrylates were synthesized by using 4, 4′- (terephthaloyldioxy) dibenzoic acid as a mesogen unit.
The application of phenylfluorone (PF)-Mo(VI) complex as a spectroscopic probe is studied. In the presence of OP microemulsion at pH 3.04, PF-Mo(VI) complex com
An efficient poly(ethylene glycol) (PEG)-supported liquid-phase parallel approach to di(aryloxyacetyl)thiosemicarbazides is described. PEG-bound phenol reacted
The multiwall carbon nanotube (MWCNT) bonded to 2, 9, 16, 23-tetraamino manganese phthalocyanine (TAMnPc) was obtained by covalent functionalization, and its ch
The effective dielectric response of linear composites containing graded material is investigated under an applied electric field Eo. For the cylindrical inclus
A numerical study was conducted for the vortex-induced vibrations of an elastic circular cylinder at low Reynolds numbers. An Arbitrary Lagrangian-Eulerian (ALE
The molecular structures of compounds (Z)-1-phenyl-1-phenylseleno-2-(p-tolylsulfonyl) ethene 1 (C21H18O2SSe, Mr = 413.37) and 1,3-diphenyl-3-phenylseleno-2-(p-t
A hyperbranched polyamidoamine polymer was synthesized on the surface of magnetite nanoparticles to enhance bovine serum albumin (BSA) immobilization efficiency
Both dependent and independent model algorithms are designed with genetic algorithm (GA) to retrieve aerosol size data from multispectral extinction measurement
The chain dynamics of a pair of diblock poly(styrene-b-butadiene) (PS210-b-PB960) and triblock poly(styrene-b-butadiene-b-styrene) (PS200-b-PB1815-b-PS200) copo