The resistance of wood-fiber paper to water, grease, and water vapor is usually attained by immersing the base paper in hydrophobic oil, laminating with a plastic or metal film, or the application of a barrier coating. Oil impregnation and the addition of films may make the paper difficult to recycle or persistent in the environment owing to their strong binding force and nondegradability. Environmental concerns have attracted worldwide attention to eco-friendly barrier coatings. In this study, degradable polyvinyl alcohol(PVA) and kaolin clay pigment were used to prepare coatings that were applied to a base paper. By measuring the barrier properties of the coated paper, including the water absorptiveness(Cobb60 value), Hercules sizing degree, oil resistance(Kit rating), and water vapor transmission rate(WVTR), an optimal coating formulation and process were proposed. To examine the barrier mechanism of the PVA/kaolin clay coating, we characterized the coating microstructures using a scanning electron microscopy(SEM) and a mercury porosimeter. The results showed that the Cobb60 value and water vapor transmission rate of the coated paper decreased by 61.4% and 98.6%, respectively, compared with the base paper, for a pre-coating weight of 0.98 g/m~2 and a top-coating weight of about 3.23 g/m~2. Furthermore, the Hercules sizing degree rose by a factor of 337.2, while the oil resistance(Kit rating) increased from 0 to 12. The optimum drying temperature for a wet coating layer was found to be 170℃, and the optimum weight ratio of PVA to kaolin clay in the coating was determined to be 50∶50. It was assumed that the PVA/kaolin clay coating improved the smoothness of the paper considerably and decreased the pore size by filling the pores on the paper surface and forming an even film, thus enhancing the paper barrier performance. The coated paper also exhibited good repulpability. The resistance of wood-fiber paper to water, grease, and water vapor is usually attained by immersing the base paper in hydrophobic oil, laminating with a plastic or metal film, or the application of a barrier coating. Oil impregnation and the addition of films may make the paper difficult to recycle or persistent in the environment owing to their strong binding force and nondegradability. Environmental concerns have been attracted to eco-friendly barrier coatings. In this study, degradable polyvinyl alcohol (PVA) and kaolin clay pigment were used To prepare coatings that were applied to a base paper. By measuring the barrier properties of the coated paper, including the water absorptiveness (Cobb60 value), Hercules sizing degree, oil resistance (Kit rating), and water vapor transmission rate (WVTR) an optimal coating formulation and process were proposed. To examine the barrier mechanism of the PVA / kaolin clay coating, we characterized the coating microstructures using as canning electron microscopy (SEM) and a mercury porosimeter. The results showed that the Cobb 60 value and water vapor transmission rate of the coated paper decreased by 61.4% and 98.6%, respectively, compared with the base paper, for a pre-coating weight of 0.98 g / m 2 and a top-coating weight of about 3.23 g / m 2. Furthermore, the Hercules sizing degree rose by a factor of 337.2, while the oil resistance (Kit rating) increased from 0 to 12. The optimum drying temperature for a wet coating was found to be 170 ° C, and the optimum weight ratio of PVA to kaolin clay in the coating was determined to be 50:50. It was assumed that the PVA / kaolin clay coating improved the smoothness of the paper considerably and decreased the pore size by filling the pores on the paper surface and forming an even film, thus enhancing the paper barrier performance. The coated paper also shows good repulpability.