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本文综述了各种羧基化剂对含有活性氢原子化合物的羧基化反应。论及;1.MMC对伯—硝基烃和活性酮的羧基化反应。2.BrMgO_2C—N(?)NCO_2MgBr对活性酮化合物的羧基化反应。3.碱金属酚盐和二氧化碳对伯硝基烃、活性酮、活性酯、以及RC≡C-H,RCH_2CN,环戊二烯,茚和硝基甲苯的羧基化反应。4 DBU和二氧化碳,DBU锂盐作为二氧化碳的载体对活性酮类的羧基化反应以及在NaH存在下(?)对伯硝基烃类的羧基化反应。
This review summarizes the carboxylation of various carboxylating agents for active hydrogen-containing compounds. Discussion; 1.MCM carboxylation of primary nitro compounds and active ketones. 2.BrMgO_2C-N (?) NCO_2MgBr on the activity of the ketone compound carboxylation. 3. Carboxylation of alkali phenoxides and carbon dioxide to primary nitrohydrocarbons, active ketones, active esters, and RC≡C-H, RCH 2 CN, cyclopentadiene, indene and nitrotoluene. 4 DBU and carbon dioxide, lithium salt of DBU as carbon dioxide support for the carboxylation of active ketones and the carboxylation of primary nitrohydrocarbons in the presence of NaH (?).