铌、钨和硼在TiAl基合金中的分布及其对组织的影响

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铌、硼和钨在TiAl基合金中的存在形式、分布状态与该合金的制备方法、加工工艺及热处理制度有密切的联系,它们对TiAl基合金的性能又有重要影响.为进一步对有关问题进行研究,该文对铌、钨、硼在TiAl基合金中的作用进行了综合分析,对铸造法制得的Ti-Al-Nb-W-B合金进行了热等静压和均匀化处理,并对微观金相组织进行了观察比较.结果表明:Ti-45Al-7Nb合金中添加少量的钨和硼,能使晶团尺寸明显细化,达40μm.随钨含量的增加,晶团尺寸越来越小,片层间距则越来越大,如Ti-45Al-7Nb-0.15B的晶团尺寸约为100μm,片层间距约为1.2μm;Ti-45Al-7Nb-0.2W-0.15B的晶团尺寸约为70 μm,片层间距约为1.6 μm; Ti-45Al-7Nb-0.4W-0.15B的晶团尺寸约为50μm,片层间距约为1.7μm Ti-45Al-7Nb-0.7W-0.15B的晶团尺寸约为40μm,片层间距约为1.8μm.钨含量达到0.4%以后,晶团细化及片层间距增加的效果便渐趋稳定.
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