七十年代以前,旋光性高分子的研究主要着眼于聚合反应本身,即企图借助旋光性单体获得立体规整聚合物,或使用手性引发剂,Ziegler-Natta型催化剂等由潜手性单体聚合以得到旋光性高分子。近十多年来,对于旋光性高分子的兴趣逐渐转到其可能的应用方面,如用做色谱法直接拆分的手性固定相及用于不对称合成的高分子化手性试剂或催化剂等。 Seventies, optical polymers mainly focus on the polymerization itself, which attempts to obtain the use of optically active monomers stereoregular polymer, or the use of chiral initiators, Ziegler-Natta-type catalyst from latent monomer Polymerization to obtain optically active polymer. Over the past decade or so, interest in optically active polymers has gradually shifted to their possible applications such as chiral stationary phases for direct resolution by chromatography and polymeric chiral reagents or catalysts for asymmetric synthesis Wait.