我们曾系统地研究了金属的双环戊二烯基二氯化物与酚的反应以及芳氧基衍生物的核磁共振谱。本文进一步研究了双(烷基环戊二烯基)二氯化钛、锆和铪同酚或取代酚的反应。在苯中,钛衍生物在氨基钠存在下迴流温度,锆和铪衍生物在三乙胺存在下室温进行反应,分子中两个氯原子均被芳氧基 We have systematically investigated the reaction of metal dicyclopentadienyl dichlorides with phenols and the nuclear magnetic resonance spectrum of aryloxy derivatives. This paper further studies the reaction of bis (alkylcyclopentadienyl) titanium dichloride, zirconium and hafnium with phenol or substituted phenol. In benzene, titanium derivatives in the presence of sodium amide reflux temperature, zirconium and hafnium derivatives react in the presence of triethylamine at room temperature, the two chlorine atoms in the molecule are the aryloxy