【摘 要】
:
SnO2 is considered to be a promising candidate as anode material for lithium ion batteries,due to its high theoretical specific capacity(1494 mAh·g-1).Neverthe
【机 构】
:
School of Chemistry and Materials Science,Jiangsu Normal University,Xuzhou 221116,China;Institute of
论文部分内容阅读
SnO2 is considered to be a promising candidate as anode material for lithium ion batteries,due to its high theoretical specific capacity(1494 mAh·g-1).Neverthe-less,SnO2-based anodes suffer from poor electronic con-ductivity and serious volume variation(300%)during lithiation/delithiation process,leading to fast capacity fading.To solve these problems,SnO2 quantum dots modified N-doped carbon spheres(SnO2 QDs@N-C)are fabricated by facile hydrolysis process of SnCl2,accom-panied with the polymerization of polypyrrole(PPy),fol-lowed by a calcination method.When used as anodes for lithium ion batteries,SnO2 QDs@N-C exhibits high dis-charge capacity,superior rate properties as well as good cyclability.The carbon matrix completely encapsulates the SnO2 quantum dots,preventing the aggregation and volume change during cycling.Furthermore,the high N content produces abundant defects in carbon matrix.It is worth noting that SnO2 QDs@N-C shows excellent capacitive contribution properties,which may be due to the ultra-small size of SnO2 and high conductivity of the car-bon matrix.
其他文献
石墨烯由于具有超高强度、刚度以及优异的热学和电学性能,被认为是金属基复合材料的理想增强相.本文采用常压烧结法制备了石墨烯增强铜基纳米复合材料.采用电镜观察以及其它
通过富氩气体保护焊方法,采用直径为1.2 mm的JM-110实芯焊丝对3 mm厚的HC500和HC950汽车用高强钢板进行搭接焊,并对接头金相组织进行了观察,对接头剪切拉伸强度、硬度等力学
The uniaxial tensile tests were carried out at temperature ranging from room temperature(RT)to 523 K under strain rates of 0.001,0.010 and 0.100 s-1 to obtain t
LiVPO4F has attracted increasing research interest in the field of Li-ion batteries due to its high working voltage platform and high theoretical energy density
In order to prove that the Te-based glass frit could be applied to Ag pastes to fabricate Ag electrode and elucidate the reactions among Ag,the frit,and the Si
CeO2 is one of the main catalysts for solid oxide fuel cell(SOFC).It is critical to find a green and cost-effective fabrication method for CeO2 at scale.In this
Battery technologies have obtained great attention due to their wide-ranging applications in present and emerging fields[1,2],and great progress in exploring no
Yb3+and Er3+were doped into Y2O3 to form Y2O3∶Yb3+,Er3+microcrystals.The effect of doping concentration of Yb3+was studied.The near-ultraviolet(UV)upconversion
Aluminum phosphate(AlPO4)was used to modify the surface of LiNi1/3Co1/3Mn1/3O2(NCM)cathode material.The surface structure and electrochemical prop-erties of the
The p-type TiCoSb-based half-Heuslers are widely studied due to the good electrical transport prop-erties after hole doping,while the pristine TiCoSb is intrins