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Dicyanide building block cis-Fe(phen)_2(CN)_2 and [Mn~Ⅲ(salen)](ClO_4) have been used to design and synthesize a cyanide-bridged complex, resulting in a heterobimetallic one-dimensional(1D) zigzag chain complex 1, [cis-Fe(phen)_2(CN)_2Mn(salen)](PF_6)(phe