本文研究了在Pd(PPh_3)_2Cl_2(1)催化下的三正丁基-2-呋喃基锡(6a),三正丁基-2-噻吩基锡(6b),三正丁基-2-(N-甲基)吡咯基锡(6c)和菊酰氯(5),肉桂酰氯(7)的交联反应.发现除了三正丁基-2-(N-甲基)吡咯与5的不寻常反应得到2,5-二取代的吡咯衍生物外,其余反应皆以70～87％的产率得到交叉偶联产物.本文同时还报道了钯催化下有机锡试剂与取代卤代芳烃反应,高收率地得到了不对称的杂环基芳烃和双杂环化合物.在合成的交联产物中,化合物2,8,9,15,16与17均为新化合物. In this paper, the effects of tri-n-butyl-2-furyltin (6a), tri-n-butyl-2-thienyltin (6b), tri-n-butyl-2- (N-methyl) pyrrolyltin (6c) and chrysantheryl chloride (5) and cinnamoyl chloride (7) Reaction gave 2,5-disubstituted pyrrole derivatives, the rest of the reactions were obtained in 70 ~ 87% yield of cross-coupling products.In this paper, we also reported the palladium-catalyzed reaction of organotin reagents with substituted halogenated aromatic hydrocarbons, high Asymmetric heterocyclic heterocycles and two-ring heterocyclic compounds were obtained in a good yield.In the synthesized cross-linked products, compounds 2, 8, 9, 15, 16 and 17 were all new compounds.