【摘 要】
:
The title compound {η5:η1-[(2-MeOC6H4)C3H6]C9H6}Li(DME) (DME = 1,2-dimethoxy-ethylene) was synthesized by the treatment of 3-[(2-methoxyphenyl)-isopropyl]-ind
【机 构】
:
Institute of Organic Chemistry,State Key Laboratory of Organometallic Chemistry,Fujian Institute of
论文部分内容阅读
The title compound {η5:η1-[(2-MeOC6H4)C3H6]C9H6}Li(DME) (DME = 1,2-dimethoxy-ethylene) was synthesized by the treatment of 3-[(2-methoxyphenyl)-isopropyl]-indene with 1 equiv. of n-BuLi followed by the recrystallization from a mixed solution of toluene and DME.The compound crystallizes in orthorhombic system, pace group Pbca with a = 14.5677(3), b = 15.54670(10), c = 18.7498(3) (A), Z = 8, V = 4246.45(11) (A)3, Dc = 1.127 g/cm3 andμ(MoKα) = 0.072 mm- 1. The coordination geometry can be described as a distorted tetrahedron.
其他文献
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
Herein, we report the cloning and molecular characterization of a full cDNA encoding a putative plastidic ATP/ADP transporter, designated HtAATP, for Helianthus
The roots of Anemone altaica Fisch. ex C. A. Mey. have been used in the treatment of epilepsia,neurasthenia, and arthritis in Chinese folk medicine for a long t
The synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide using potassium hydroxide as catalyst in the presence of CH3I and the effect of ionic
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
Different hydroxy substituted coumarins were successfully phosphorylated with diisopropylphophite (DIPPH) by the Atherton-Todd reaction in 76-89% yields. Moreov
29 aromatic compounds were computed at the HF/6-31G* level. Based on linear solvation energy theory firstly, the parameters of molecular structure were taken as
It was reported for the first time that phosphorictungstenic acid (PWA) could promote the oxygen reduction reaction (ORR) and inhibit the methanol oxidation rea
Kinesins and kinesin-like proteins (KLPs) constitute a large family of microtubule-based motors that play important roles in many fundamental cellular and devel