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Flash pyrolysis of MnTC([Mn2(TNR)2(CHZ)2(H2O)4]·2H2O) and NiCT([Ni(CHZ)3](TNR)·5H2O) is conducted by using T-jump/FTIR spectroscopy under 0.1 MPa Ar atmosphere. The mole fractions of the individual products in the pyrolysis gas mixture are descr