Enhanced Electrocatalytic Activity by RGO/MWCNTs/NiO Counter Electrode for Dye-sensitized Solar Cell

来源 :Nano-Micro Letters | 被引量 : 0次 | 上传用户:jeffbee
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We applied the reduced graphene oxide/multi-walled carbon nanotubes/nickel oxide(RGO/MWCNTs/Ni O)nanocomposite as the counter electrode(CE) in dye-sensitized solar cells(DSSCs) on fluorine-doped tin oxide substrates by blade doctor method. Power conversion efficiency(PCE) of 8.13 % was achieved for this DSSCs device, which is higher than that of DSSCs devices using Ni O, RGO, and RGO/Ni O-CE(PCE = 2.71 %, PCE = 6.77 % and PCE = 7.63 %). Also, the fill factor of the DSSCs devices using the RGO/MWCNTs/Ni O-CE was better than that of other CEs. The electron transfer measurement of cyclic voltammetry and electrochemical impedance spectroscopy showed that RGO/MWCNTs/Ni O film could provide fast electron transfer between the CE and the electrolyte, and high electrocatalytic activity for the reduction of triiodide in a CE based on RGO/MWCNTs/Ni O in a DSSC. We applied the reduced graphene oxide / multi-walled carbon nanotubes / nickel oxide (RGO / MWCNTs / NiO) nanocomposite as the counter electrode (CE) in dye-sensitized solar cells (DSSCs) on fluorine-doped tin oxide substrates by blade doctor The power conversion efficiency (PCE) of 8.13 was was for this DSSCs device, which is higher than that of DSSCs devices using NiO, RGO, and RGO / Ni O-CE (PCE = 2.71%, PCE = 6.77% and PCE = 7.63%). Also, the fill factor of the DSSCs devices using the RGO / MWCNTs / Ni O-CE was better than that of other CEs. The electron transfer measurement of cyclic voltammetry and electrochemical impedance spectroscopy showed that RGO / MWCNTs / Ni O film could provide fast electron transfer between the CE and the electrolyte, and high electrocatalytic activity for the reduction of triiodide in a CE based on RGO / MWCNTs / NiO in a DSSC.
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