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A novel super molecule [Na(C60H80O12)]+- was obtained by ext raction of calix arene (L) for an aqueous solution containing -, and N aCl into CH2Cl2. The crystal structure and properties of the title super molecul e were characterized by single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragon al system with space group P4/n and the unit cell parameters were as follows: a= 2.880 8(18) nm, b=2.880 8(18) nm, c=2.292 4(5) nm, and final R indices : R1=0.048 5, wR2=0.106 1. CCDC: 243229.
A novel super molecule [Na (C60H80O12)] + was was used by ext raction of calix arene (L) for an aqueous solution containing -, and NaCl into CH2Cl2. The crystal structure and properties of the title super molecul e were characterized by Single-crystal X-ray diffraction, IR and 1H NMR spectra. The X-ray single crystal structure analysis shows that the crystal was Tetragon al system with space group P4 / n and the unit cell parameters were as follows: a = 2.880 8 ( 18) nm, b = 2.880 8 (18) nm, c = 2.292 4 (5) nm, and final R indices: R1 = 0.048 5, wR2 = 0.106 1. CCDC: 243229.