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Presented here is a new heterometallic Cu(I)-Sr(Ⅱ) coordination polymer, [Cu(3)Sr2(isonic)5 Br2(H2O)3]n·n(H2O)(1, Hisonic = isonicotinic acid), has been synthesized via the hydrothermal reactions of CuBr, Sr(NO3)2 and isonicotinic acid. The crystal s