为了将手征性分子表现出来的旋光性与分子的构型密切联系起来,我们先后提出了不对称碳原子周围极化度的多级圆球不对称性模型以及旋光性构型的概念。较为成功地把非极性溶剂中含有一个不对称碳原子的化合物的分子构型与其旋光方向密切地联系起来了。如果化合物分子中含有两个手性碳,其分 In order to closely relate the optical activity exhibited by the chiral molecules to the molecular configuration, we have successively proposed the multistage sphere asymmetry model and the concept of optical configuration of the asymmetry around the carbon atoms. The successful combination of the molecular configuration of a compound containing an asymmetric carbon atom in a non-polar solvent with its direction of rotation is more successful. If the compound contains two chiral carbon molecules, its points