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1981年第一个含碳硅双键的化合物被分离出来.但这类化合物在通常条件下是不稳定的,易于发生加成、异构化反应.Conlin给出了甲基硅乙烯异构化反应的实验证据.近来Davidson和Conlin又对反应(1)进行了热力学、动力学观测,实验表明反应(1)只
The first compound with carbon-silicon double bonds was isolated in 1981. However, these compounds are unstable under normal conditions and tend to undergo addition and isomerisation reactions. Conlin gives isomerisation of methylsiloxane Experimental Evidence of Reaction. Recently, Davidson and Conlin again conducted a thermodynamic and kinetic study of reaction (1). Experiments show that the reaction (1) only