Infinite Three-Dimensional Coordination Polymers: Synthesis and Structures of [Cd (4,4'-bpy)2 (

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Three Complexes of the formula [ Cd (4,4-bpy)2 (H2O)2 ]n (pic)2n (1), [ Zn (4,4-bpy)2 (H2O)2 ]n-(pic)2n (H2O)2n (2) and [ Zn (4,4-bpy)2 (H2O)2 ]n (4,4-bpy)n (pic)2n (H2O)n (3) ( 4,4-bpy = 4,4-bipyridine; pic = picric anion ) have been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. They all have infinite three-dimensional network structure, crystallizing in the monoclinic space group C2/c (1) and Cc (2,3).
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