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微波溶解地质样品已有一些报道。Mathes在塑料瓶中溶解矿物试样;Nadkarni在加盖的Teflon杯中分解岩石和沉积物标样;Lamothe在聚氨酯瓶中分解了51种地质标准参考样;Bouvier等在Teflon-PFA容器中分解了Cu/Ni硫化物试样;徐立强等在密闭聚四氟乙烯(PTFR)罐中分解了水系沉积物并用ICP-AES测定了多种元素。这些方法的共同点是用HNO_3+HF或HNO_3+HF+H_2O_2分解试样,加入过量的H_3BO_3络合剩余的HF,然后再进行测定。由于H_3BO_3溶解度较小,而且为了降低最后试液中的盐类浓度以免堵塞ICP-AES仪的雾化器喷咀,都将溶样后的试液进行了高倍数的稀释。但是,试液的高度稀释使一些痕量元素难于用原子光谱法测
Microwave dissolution of geological samples have been reported. Mathes dissolves mineral specimens in plastic bottles; Nadkarni decomposes rock and sediment standards in capped Teflon cups; Lamothe decomposes 51 geologic-standard reference samples in polyurethane bottles; Bouvier et al. Decompose in Teflon-PFA containers Cu / Ni sulfide samples; Xu Liqiang et al. Decomposed aqueous sediments in sealed polytetrafluoroethylene (PTFR) tanks and determined various elements by ICP-AES. The common point of these methods is to decompose the sample with HNO 3 + HF or HNO 3 + HF + H 2 O 2, add excess H 3 BO 3 to complex the remaining HF, and then measure. Due to the low solubility of H_3BO_3, and in order to reduce the concentration of salts in the final test solution so as not to clog the atomizer nozzle of the ICP-AES instrument, the diluted test solution was diluted by a factor of high. However, the high dilution of the test solution makes it difficult to measure some trace elements by atomic spectroscopy