Low-temperature heat capacities and standard molar enthalpy of formation of pyridine-2,6-dicarboxyli

来源 :Chinese Physics B | 被引量 : 0次 | 上传用户:kmask
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K.A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method.Based on the fitted polynomial,the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K.The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter.The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion.The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle. This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 KA polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cy cle.
其他文献
By cavitation tests and scanning electron microscope (SEM) microanalysis,the micro-appearance of cavitation samples is studied. It is the first time that the mi
L北京单片机联谊会剃工次专题付论会在东道上仁包手技木应用*杂志社的热心承办下。顺利地完成了首届大驯:讨恬劝。32位秘…处理器、嵌人式to ny、乞OC成力了本次会议的中心议
庞之浩,1957年出生,浙江绍兴人,毕业于北京邮电学院。毕业后被分配在北京市仪表局所属北京无线电仪器厂设计所工作,1986年调入中国空间技术研究院所属北京空间科技信息研究所
谢·罗便臣女士(Jill Robinson)1936年出生于英格兰,自幼喜爱动物。1987年她进入国际爱护动物基金会(IFAW),并为IFAW工作长达11年。1998年,她离开IFAW,在香港创办了专门针对
苏霍姆林斯基曾说过,学习如果具有思想、感情、创造、美和游戏的鲜艳色彩,那它就能成为孩子们深感兴趣和富有吸引力的事情.笔者是“情智数学课堂”的倡导者和践行者,一直主张
期刊
两江国际影视城,位于重庆龙兴古镇的腹地,一个隽永而清秀的地方。沿着弯曲的山路,绕过一片起伏的山峦,隔着薄薄云雾,一排排的青砖瓦房跃入眼帘。略显灰黯的建筑,仿佛经历了上
Fluctuation theorem for entropy production in a mesoscopic chemical reaction network is discussed. When the system size is sufficiently large, it is found that,
为了提高森林调查的精度和效率我们于1978年设计了“定角样地调查法”,並进行了一些试验,从试验结果看,用该法所测定的森林蓄积量、株数、平均直径等项因子的精度稳定可靠。
在一些小型渡口,人们会用各种各样的办法渡水。有趣的是,那些摆渡的船夫并不全是人类。  猴子渡:在非洲的扎伊尔有个猴子渡口。渡船是木筏,每个筏子上有七八只猴子撑船和划桨。如果有人不幸落水,它们还会立即跳进河中把人救起。  鳄鱼渡:扎伊尔还有个远近闻名的“鳄鱼渡”。这里的渔民卢巴苏库曾从蟒蛇口中救出一条幼小的鳄鱼,从此每次外出打鱼都带着它。20多年后,主人渐老,而鳄鱼却正值壮年,身长2米多,力大无比。
宣城森泰公司用高品位磷矿 (P2 O52 8% )、湿法工艺生产过磷酸钙 ,产品有效 P2 O5为 13 %~ 15 % ,但水分偏高 ,有时在 15 %以上。根据行业标准 HG 2 740 95的规定 ,过磷酸钙属