In this paper we calculate the production of a charged top pion in association with a W boson at the CERN Large Hadron Collider (LHC) in the context of the topcolor assisted technicolor model. We find that the cross section of pp → b(-b) → W±π(干)t is roughly corresponding to the result of the process pp → b(-b) → W±H(干) in the minimal supersymmetric standard model, and for reasonable ranges of the parameters, the cross section can reach a few hundred fo. The W±π(干)t signal should be clearly visible at LHC unless π±t is very heavy.