Preparation of nano-sized cerium and titanium pyrophosphates via solid-state reaction at room temper

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Nano-sized cerium-titanium pyrophosphates Ce1-xTixP2O7 (with x=0, 0.2, 0.5, 0.7, 0.9, and 1.0) were obtained by grinding a mixture of to remove soluble inorganic salts, and drying at 100℃. The products and their calcined samples were characterized using ultraviolet-visible spectroscopy (UV-vis), therrnogravimetry and differential thermal analyses (TG/DTA), X-ray powder diffraction (XRD), and transmission electron microscopy (TEM). The results show that nano-sized Ce1-xTixP2O7 behave as an excellent UV-shielding material. Thereinto, the CeP2O7 has the most excellent UV-shielding effect, and the amorphous state of Ce038Ti0.2P2O7 can keep at a higher temperature than CeP2O7. Therefore, the stabilization of the amorphous state of the cerium pyrophosphates was carried out by doping titanium. This stabilization is a significant improvement, which enables to apply these amorphous pyrophosphates not only to cosmetics and paints, but also plastics and films.
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