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用水热法合成了2个化合物[M2(L)(phen)2(H2O)2]·6H2O[M=Ni(1),Zn(2),H4L=4,4′-联吡啶-2,2′,6,6′-四羧酸,phen=1,10-邻菲咯啉],并进行了元素分析、IR及X-射线单晶结构测定等表征。晶体结构解析结果表明:配合物1和2的晶体都属于三斜晶系,P1空间群。配合物的中心金属离子都是六配位变形的八面体配位构型,配体4,4′-联吡啶-2,2′,6,6′-四羧酸的羧基均以单齿形式配位。室温固体荧光测试结果显示配合物2具有较强的荧光。
Two compounds [M2 (L) (phen) 2 (H2O) 2] · 6H2O [M = Ni (1) Zn (2) and H4L = 4,4’-bipyridine-2,2 ’, 6,6’-tetracarboxylic acid, phen = 1,10-phenanthroline] were synthesized and characterized by elemental analysis, IR and X-ray single crystal structure determination. Crystal structure analysis results show that: the complexes 1 and 2 belong to triclinic crystal system, P1 space group. The central metal ions of the complex are hexacoordinately distorted octahedral coordination configuration. The carboxyl groups of the 4,4’-bipyridine-2,2 ’, 6,6’-tetracarboxylic acid are all monodentate Coordination. The results of solid-state fluorescence test at room temperature show that complex 2 has strong fluorescence.