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A heterometallic 4f-5d inorganic-organic metal-isonicotinato hybrid Gd(C6NO2H5)3-(H2O)22n·(nH5O2)(nHgCl5)(2nHgCl4)·(2nH2O) 1 has been synthesized via hydrothermal reaction and structurally characterized.Complex 1 crystallizes in the space group C2/c of monoclinic system with four formula units in a cell:a=24.234(8)=b=20.816(7)=c=15.333(3)=β=128.091(8)°=V=6088(3)3=C36H47Cl13Gd2Hg3N6O20=Mr=2260.92=Dc=2.467 g/cm3=S=0.896=μ(MoKα)=10.331 mm-1=F(000)=4216=R=0.0344 and wR=0.0629.The crystal structure analysis reveals that the title complex is characteristic of a one-dimensional chain-like structure.Photoluminescent investigation reveals that the title complex displays a broad and intense emission in the green region.
A heterometallic 4f-5d inorganic-organic metal-isonicotinato hybrid Gd (C6NO2H5) 3- (H2O) 22n · (nH5O2) (nHgCl5) (2nHgCl4) · (2nH2O) 1 has been synthesized via hydrothermal reaction and structurally characterized. Complex 1 crystallizes in the space group C2 / c of monoclinic system with four formula units in a cell: a = 24.234 (8) = b = 20.816 (7) = c = 15.333 = β = 128.091 ° = V = 6088 3 = C36H47Cl13Gd2Hg3N6O20 = Mr = 2260.92 = Dc = 2.467 g / cm3 = S = 0.896 = μ (MoKα) = 10.331 mm -1 = F (000) = 4216 = R = 0.0344 and wR = 0.0629. crystal structure analysis reveals that the title complex is characteristic of a one-dimensional chain-like structure. Photoluminescent investigation reveals that the title complex display a broad and intense emission in the green region.