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芳香和脂肪酰胺在甲苯或乙腈中加入不同的醛以及三乙基硅烷和三氟乙酸 ,回流 1 6 h可得相应的 N-烷基化酰胺 ,该法广泛适用于硫代酰胺脲和氨基甲酸酯 (制备伯胺 )等 ,2 1例收率 46 %～ 97%。酰胺及其类似物的还原N-烷基化@Dube D@张贞发
Aromatic and fatty amides in toluene or acetonitrile by adding different aldehydes and triethylsilane and trifluoroacetic acid reflux 16 h available N-alkylated amide, the method is widely used in thioamide and ammonia methyl Acid ester (for the preparation of primary amine), 21 cases yield 46% ~ 97%. Reduced N-Alkylation of Amides and Their Analogues